Semi-transparent Ultra-flexible Organic Photovoltaics via Thin Multilayer Electrodes
- 주제(키워드) ultra-flexible device , transparent photovoltaics , transparent conducting electrode , ultrathin photonic devices.
- 주제(DDC) 621.381
- 발행기관 아주대학교
- 지도교수 박성준
- 발행년도 2022
- 학위수여년월 2022. 8
- 학위명 석사
- 학과 및 전공 일반대학원 전자공학과
- 실제URI http://www.dcollection.net/handler/ajou/000000031984
- 본문언어 영어
- 저작권 아주대학교 논문은 저작권에 의해 보호받습니다.
초록/요약
The development of ultra-flexible metal electrode (UME) is an essential to expand the optical science and engineering capabilities of flexible optoelectronic devices. In application of functional devices, the in-depth studies on novel UME layer, including mechanical, optical, and electrical analysis are prerequisite. With nano-scale thickness modulation of Ag thin metal layer, we analyzed different thickness of deposited films. As a result, the deposited layer exhibits >80% transparency at 380-825 nm, and sheet resistance <12 ohm/square. In addition, their mechanical robustness was improved under 66% compressive stress with repetitive cycling test over 103. Because the UME has good mechanical stability with both high transmittance and conductivity, the suggested electrodes can be applied into organic photovoltaics (OPVs) as a bottom and top electrodes. The fabricated ultra-flexible semi-transparent OPVs shows highest average visible transmittance (AVT) of 30.1 % and power-conversion-efficiency (PCE) of 6.93 % with high mechanical durability over 1000 cycles, comparative to those of OPVs using ITO electrodes. The results show their great potentials of the ultra-flexible ST-OPV, facilitating the road to the future for a variety of applications.
more목차
1. Introduction (Background) 1
2. Experimental Section and Methods 6
2.1 Materials 6
2.2 Electrode and Device Fabrication 8
2.3 Mechanical property and Characteristics 9
2.4 Organic Photodiode Operation Property 11
3. Results and Discussion 14
3.1 Design of the Stretchable Semi-transparent Organic Photovoltaic Cells 14
3.2 The optical and electrical characteristics of transparent electrodes 21
3.3 Stretchable transparent electrode with Ag films 33
3.4 Ultra-flexible ST-OPVs Structure 40
4. Conclusion 52
Reference 54